课题组简介：

本课题组主要从事纺织化学相关的基础和应用研究，主要研究方向为利用细乳液、乳液及悬浮等非均相反应技术，制备新型功能微/纳米材料，并通过对材料结构的合理设计和可控合成，来提升其在纺织品功能整理、印染废水处理等领域的应用价值。承担国家级项目3项，省部级项目及企业委托项目多项，在国内外重要学术期刊上发表SCI收录论文60余篇，授权发明专利10余件。目前在读博士生3人，硕士生8人，已培养硕士研究生6人，其中多人获浙江省优秀硕士学位论文和校优秀硕士学位论文称号。

课题组成员：

曹志海，浙江余杭人，工学博士，教授，博士生导师，省高校中青年学科带头人。分别于2002年、2005年及2009年，在浙江大学化工系取得工学学士、工学硕士和工学博士学位，三次获得浙江大学和浙江省优秀毕业生称号。攻读博士期间，在国家留学基金委资助下，赴法国国家科研中心里昂一大聚合化学与过程实验室交流学习一年，师从有机-无机杂化材料领域的国际知名学者Bourgeat-Lami E.研究员。2009年6月，赴德国乌尔姆大学化学系从事博士后研究工作，合作导师为细乳液聚合领域的国际级权威Landfester K.教授和Ziener U.教授。2010年12月回国，任职于杭州师范大学材料与化学化工学院。2014年10月以特聘教授身份调入浙江理工大学。

主要从事纺织化学相关的基础和应用研究，主要研究方向为利用细乳液、乳液及悬浮等非均相反应技术，制备新型功能微/纳米材料，并通过对材料结构的合理设计和可控合成，来提升其在纺织品功能整理、印染废水处理和生物等领域的应用价值。

目前，以第一或通讯作者身份在Macromolecules、Dyes and Pigments、Nanoscale、Journal of Material Chemistry C、Polymer Chemistry、Advances in Colloid and Interface Science、Langmuir、Journal of Polymer Science, Part A: Polymer Chemistry等国内外期刊上发表SCI/EI收录论文60余篇，获得国家发明专利10件。主持国家自然科学基金面上和青年项目、省重点研发计划课题、省自然科学基金、省公益性技术应用研究计划、企业委托项目等多个项目。担任教育部高等学校科学研究优秀成果奖、省自然科学基金项目、Nanoscale、Journal of Material Chemistry、Langmuir、Polymer Chemistry、Dyes and Pigments等众多国内外期刊的评审人。指导大学生获得国家大学生创新计划3项，浙江省新苗计划4项。指导研究生获校和学科优秀硕士学位培育基金3项，指导完成浙江省优秀硕士学位论文1篇，校优秀硕士学位论文3篇，研究生获包括国家奖学金在内的各种奖项多次。

秘一芳，博士，讲师。2018年毕业于浙江大学高分子系，同年进入浙江理工大学轻化工程专业任职。研究方向：功能化膜材料的设计、开发及分离膜过程和应用研究。主持国家自然科学基金青年项目1项，以主要成员身份参与国家自然科学基金、国家重点基础研发计划和浙江省杰出青年项目等多个项目。在Journal of Membrane Science、Separation and Purification Technology、Polymer Chemistry、Colloids and Surfaces A、Journal of Applied Polymer Science等期刊发表SCI收录论文多篇，获国家发明专利1件。

代表性论文：

1. Liang, X. Q.; Tao, M.; Wu, D.; Yu, B.; Mi, Y. F.; Cao, Z. H.; Zhao, Z. J.; Chen, D. Z. Multicolor AIE polymeric nanoparticles prepared via miniemulsion polymerization for inkjet printing, Dyes and Pigments 2020, 177, 108287.

2. Gao, F.; Qi, Q.; Liang, X. Q.; Wen, L. X.; Shang, Y.; Mi, Y. F.; Ziener, U.; Cao, Z. H. Fabrication of Fe₃O₄/O-carboxylmethyl chitosan magnetic particle assembly in inverse miniemulsion for loading and release of bovine setum albumin [J]. ChemistySelect 2020, 5,8344-8351.

3. Li, Y. X.; Chen, D. Z.; Cheng, X. X.; Gao, F.; Yang, X. B.; Mi, Y. F.; Zhou, Q. B.; Lan, S. X.; Cao, Z. H. Mechanistic Investigation on moisture-induced softening of poly(vinyl acetate)-stiffened polyester fabrics, J. Appl. Polym. Sci. 2020, 43, e49316.

4. Hu, Y. X.; Liang, X. Q,; Wu, D. L.; Yu, B.; Wang, Y. J.; Mi, Y. F.; Cao, Z. H.*; Zhao, Z. J.*, Towards white-light emission of fluorescent polymeric nanoparticles with a single luminogen possessing AIE and TICT properties, J. Mater. Chem. C, 2020, 8, 734-741.

5. Mi, Y. F.; Wang, N.; Qi, Q.; Yu, B.; Peng, X. D.; Cao, Z. H.; A loose polyamide nanofiltration membrane prepared by polyether amine interfacial polymerization for dye desalination, Sep. Purif. Technol. 2020, 248, 117079.

6. Mi, Y. F.; Xu, G.; Guo, Y. S.; Wu, B.; An, Q. F.; Development of antifouling nanofiltration membrane with zwitterionic functionalized monomer for efficient dye/salt selective separation, J. Membr. Sci. 2020,601,117795

7. Gao, F.; Wu, X. L.; Wu, D.; Yu, J. X.; Yao, J.; Qi, Q.; Cao, Z. H.; Cui, Q. M.; Mi, Y. F. Preparation of degradable magnetic temperature- and redox-responsive polymer/Fe3O4 nanocomposite nanogels in inverse miniemulsions for loading and release of 5-fluorouracil, Colloids Surf., A, 2020, 587, 124363.

8. Gao, F.; Mi, Y. F.; Wu, X. L.; Yao, J. Qi, Q.; Cao, Z. H. Preparation of thermoresponsive poly(N-vinylcaprolactam-co-2-methoxyethyl acrylate) nanogels via inverse miniemulsion polymerization, J. Appl. Polym. Sci. 2019, 136, 48237.

9. Hu, Y. X.; Liang, X. Q.; Zhuang, Z. Y.; Cao, Z. H.; Qi, Q.; Wang, Y. J.; Mi, Y. F.; Zhao, Z. J.; Cui, Q. M. Cell-penetrating peptide modified AIE polymeric nanoparticles by miniemulsion polymerization and application for cell fluorescence imaging, Polym. Chem. 2019, 10, 4220-4228.

10. Yao, J.; Gao, F.; Liang, X. Q.; Li, Y. X.; Mi, Y. F.; Qi, Q.; Yao, J.; Cao, Z. H. Efficient Preparation of carboxyl-functionalized magnetic polymer/Fe₃O₄ nanocomposite particles in one-pot miniemulsion systems, Colloids Surf., A, 2019, 570, 449-461.

11. Liang, X. Q.; Hu, Y. X.; Cao, Z. H.*; Xiao, L. S.; Lou, J. J.; Liu, L.; Wang, Y. J.; Zhao, Z. J.; Qi, D. M.; Cui, Q. M. Efficient synthesis of high solid content emulsions of AIE polymeric nanoparticles with tunable brightness and surface functionalization through miniemulsion polymerization, Dyes and Pigments, 2019, 163, 371-380.

12. Liang, X. Q.; Hu, Y. X.; Lou, J. J.; Cao, Z. H.*; Liu, L.; Wang, Y. J.; Zhao, Z. J.; Qi, D. M.; Cui, Q. M. Mechanistic investigation on fluorescence instability of AIE polymeric nanoparticles with a susceptible AIEgen prepared in miniemulsions, Dyes and Pigments, 2019, 160, 572-578.

13. Shang, Y.; Cao, Z. H.*; Chen, H. N.; Sun, Y. Y.; Yao, J.; Yang, L.; Qi, D. M.; Ziener, U. Influence of synthesis parameters on particle properties and catalytic activity of rice roll-like Au/SiO₂ nanocatalysts prepared in inverse miniemulsions, Colloids Surf., A, 2018, 537, 1-12.

14. Yao, J.; Cao, Z. H. ^*; Shang, Y.; Chen, Q.; Yang, L.; Zhang, Y. S.; Qi, D. M. Preparation of polymeric/inorganic nanocomposite particles in miniemulsions: II. Narrowly size-distributed polymer/SiO₂ nanocomposite particles, Colloids Surf., A, 2017, 530, 104-116.

15. Yao, J.; Cao, Z. H.^*; Chen, Q.; Zhao, S. N.; Zhang, Y. S.; Qi, D. M. Efficient preparation and formation mechanism of polymer/SiO₂ nanocomposite particles in miniemulsions. Colloid Polym. Sci. 2017, 295(7), 1223-1232.

16. Qi, D. M.; Gao, F.; Chen, Z. J.; Cui, Z. L.; Wang, G.; Wang, N. N.; Zhang, Y. S.; Qu, G.; Cao, Z. H. Preparation of Composite Films with Controlled Dispersion State of SiO₂ Nanoparticles by Using Polymer/SiO₂ Nanocomposite Particles, Colloids Surf., A, 2017, 523, 106-117.

17. Cao Z. H.; Chen H. N.; Shang Y.; Zhang Y. S.; Qi D. M.; Ziener U. Easily Recyclable and Highly Active Rice Roll-Like Au/SiO₂ Nanocatalysts from Inverse Miniemulsion. Colloids Surf., A, 2017, 517, 52-62.

18. Cao, Z. H.; Chen Q.; Chen H. N.; Chen Z. J.; Yao J.; Zhao S. N.; Zhang Y. S.; Qi D. M. Preparation of polymeric/inorganic nanocomposite particles in miniemulsions: I. Particle formation mechanism in systems stabilized with sodium dodecyl sulfate, Colloids Surf., A, 2017, 516, 199-210.

19. Cao, Z. H.; Liang, X. Q.; Chen, H. N.; Gao, M.; Zhao, Z. J.; Chen, X. L.; Xu, C.; Qu, G.; Qi, D. M.; Tang, B. Z., Bright and biocompatible AIE polymeric nanoparticles prepared from miniemulsion for fluorescence cell imaging. Polym. Chem. 2016, 7(35), 5571-5578.

20. Qi, D. M.; Liu, C. H.; Chen, Z. J.; Chen, H. N.; Huang, C. J.; Cao, Z. H.*, Formation mechanism of guava-like polymer/SiO₂ nanocomposite particles in in situ emulsion polymerization systems. Colloids Surf. A 2016, 489, 265-274.

21. Cao, Z. H.*; Chen, H. N.; Zhu, S. D.; Chen, Z. J.; Xu, C.; Qi, D. M.*; Ziener, U., Inverse miniemulsion-based preparation of raspberry-like Au/SiO₂ nanocomposite particles with high catalytic activity towards reduction of p-nitrophenol. Colloids Surf. A 2016, 489, 223-233.

22. Sihler, S.; Schrade, A.; Cao, Z. H.; Ziener, U. Inverse Pickering emulsions with droplets size below 500 nm. Langmuir 2015, 31(38), 10392-10401.

23. Cao, Z. H.; Xu, C.; Liang, L. H.; Zhao, Z. J.; Chen, B.; Chen, Z. J.; Chen, H. N.; Qu, G.; Qi, D. M.; Shan, G. R.; Ziener, U., A green miniemulsion-based synthesis of polymeric aggregation-induced emission nanoparticles. Polym. Chem. 2015, 6(35), 6378-6385.

24. Cao, Z. H., Chen, H. N.; Zhu, S. D.; Zhang, W. W.; Wu, X. F.; Shan, G. R.; Ziener, U.; Qi, D. M*. Preparation of Janus Pd/SiO₂ Nanocomposite Particles in Inverse Miniemulsions. Langmuir 2015, 31(14), 4341-4350.

25. Cao, Z. H.; Xu, C.; Ding, X. X.; Zhu, S. D.; Chen, H. N.; Qi, D. M. Synthesis of Fragrance/Silica Nanocapsules through a Sol-Gel Process in Miniemulsions and Their Application as Aromatic Finishing Agents, Colloid Polym. Sci. 2015, 293(4), 1129-1139.

26. Qi, D. M.; Liu, C. H.; Chen, Z. J.; Dong, G. F.; Cao, Z. H*. In Situ Emulsion Copolymerization of Methyl Methacrylate and Butyl Acrylate in the Presence of SiO₂ with Various Surface Coupling Densities, Colloid Polym. Sci. 2015, 293(2), 463-471.